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Technical Bulletins page title

No. 9
Laskin Nozzle Generator Conversion from DOP to PAO

Frequently, ATI customers ask: What is necessary to convert my TDA-4 series or TDA-6 series Laskin Nozzle Aerosol Generator to Poly-Alpha Olefin (PAO)? Most Government agencies and departments are changing from DOP to PAO because DOP has been put on the suspected carcinogen list.

Since Dr. Hugh Carlon of the Army Chemical Center has completed research on Emery 3004, the Surgeon General has accepted PAO as an acceptable substitute for DOP in the U.S. Army. The Department of Energy and their various test sites, along with the Food and Drug Administration, are also accepting PAO as a replacement for DOP. Research conducted by the Army Chemical Center and Dr. Hugh Carlon has also proven that PAO is safe.

To convert TDA-4 series or TDA-6 series Generators from DOP to PAO:

  1. Drain the existing DOP liquid from the unit.
  2. Fill the reservoir to approximately half way on the sight gauge with PAO liquid.
  3. Drain the reservoir to eliminate any residue DOP remaining in the reservoir.
  4. Refill the reservoir to approximately half way on the sight gauge with PAO.
  5. Operate the unit as normal.

Correction Factors

As long as systems are tested in the normal manner, no adjustments are required. However, adjustment will be required if a situation should arise where the photometer used for detection is calibrated to DOP, the generator contains PAO, and the use of the Internal Reference is necessary. The reason is that PAO has a different refractive index and gives a different photometric response than DOP. Therefore, a factor (of DOP) must be incorporated to insure accuracy if an upstream sample cannot be obtained to establish a 100% baseline and the Internal Reference must be used with a photometer that is not calibrated with the same liquid used in the generator. Performance Review, the technical journal of the Controlled Environment Testing Association, contains an article detailing the particulars on factors and adjustments required. This article was published in the Winter of 1993, Volume 1, No. 2. A copy can be obtained by calling CETA at (202) 737-0204.

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